原著論文

57) Enzyme model-catalyzed oxidative polymerization of 5-cyano-2-methoxyphenol, a new phenolic monomer with cyano substituent

Shimon Takechi, Takahiro Oshima, Akiyuki Nakano, Hideyuki Higashimura

Chem. Lett. 2024, 53, upae007.

 

56) Enzyme-inspired catalysts with high activity and selectivity for oxidative polymerization of 2-phenylphenol

 Akiyuki Nakano, Vivek S. Raut, Naoki Asao, Akane Ando, Kiyoshi Fujisawa, Hideyuki Higashimura

 Catal. Sci. Technol., 2023, 13, 4968.

 

55) Enzyme Model-catalyzed Oxidative Copolymerization of Phenol while Continuously Adding an Endcap to Multi-branched Poly(phenylene oxide) Showing Low Dielectric Constant

 Akiyuki Nakano, Yuto Kubota, Noboru Osaka, Hideyuki Higashimura

 Chemistry Letters, 2022, 51, 420.

 

54) A new poly(arylene oxide) with an extremely low dielectric constant as a fully aromatic hydrocarbon-type polymer

  Nakano, Akiyuki; Tanabe, Yoichi; Higashimura, Hideyuki

  Polymer, 2021, 237, 124345

 

53) Design and Synthesis of Porous Coordination Polymers with Expanded One-Dimensional Channels and Strongly Lewis-Acidic Sites

   Kajiwara, Takashi; Higashimura, Hideyuki; Higuchi, Masakazu; Kitagawa, Susumu

   ChemNanoMat, 2018, 4, 103-111.

 

52) Construction of Pt complex within Zr-based MOF and its application for hydrogen production under visible-light irradiation.

   Toyao, Takashi; Saito, Masakazu; Dohshi, Satoru; Mochizuki, Katsunori; Iwata, Masatoshi; Higashimura, Hideyuki; Horiuchi, Yu; Matsuoka, Masaya.

   Res. Chem. Intermed., 2016, 42, 7679–7688.

 

51) Synthesis, Properties, and Polymerization of Spiro[(dipyridinogermole) (dithienogermole)].

   Murakami, Kazuya; Ooyama, Yousuke; Higashimura, Hideyuki; Ohshita, Joji.

   Organometallics, 2016, 35, 20−26.

 

50) Cobalt Phenanthroline-Indole Macrocycles as Highly Active Electrocatalysts for Oxygen Reduction.

   Quernheim, Martin; Liang, Haiwei; Su, Qi; Baumgarten, Martin; Koshino, Nobuyoshi; Higashimura, Hideyuki; Müllen, Klaus.

   Chem. Eur. J., 2014, 20, 14178-14183. (Hot Paper)

 

49) A Systematic Study on the Stability of Porous Coordination Polymers against Ammonia.

   Kajiwara, Takashi; Higuchi, Masakazu; Watanabe, Daisuke; Higashimura, Hideyuki; Yamada, Teppei Yamada; Kitagawa, Hiroshi.

   Chem. Eur. J., 2014, 20, 1-8.

 

48) Distibylation of Arylacetylenes for the Formation of Bis(stibyl)ethenes.

   Ohshita, Joji; Tsuchida, Takeshi; Murakami, Kazuya; Ooyama, Yousuke; Nakanishi, Takayuki; Hasegawa, Yasuchika; Kobayashi, Norifumi; Higashimura, Hideyuki.

   Z. Naturforsch., 2014, 69b, 1181-1187

 

47) Development of a Ru Complex-Incorporated MOF Photocatalyst for Hydrogen Production under Visible-Light Irradiation.

   Toyao Takashi; Saito Masakazu; Dohshi Satoru; Mochizuki Katsunori; Iwata Masatoshi; Higashimura, Hideyuki; Horiuchi Yu; Matsuoka Masaya.

   Chem. Commun., 2014, 50, 6779-6781.

 

46) Synthesis and Properties of Nitrogen-Introduced Phenylazomethine Ddendrimer.

   Albrecht, Ken; Higashimura, Hideyuki; Yamamoto, Kimihisa.

   Synth. Commun., 2014, 44, 2239-2247.

 

45) Synthesis of Group 14 Dipyridinometalloles with Enhanced Electron-Deficient Properties and Solid-State Phosphorescence.

   Ohshita, Joji; Murakami, Kazuya; Tanaka, Daiki; Ooyama, Yousuke; Mizumo, Tomonobu; Kobayashi, Norifumi; Higashimura, Hideyuki; Nakanishi, Takayuki; Hasegawa, Yasuchika.

   Organometallics, 2014, 33, 517-521.

 

44) One-Dimensional Alignment of Strong Lewis Acid Sites in a Porous Coordination Polymer.

   Kajiwara, Takashi; Higuchi, Masakazu; Yuasa, Akihiro; Higashimura, Hideyuki; Kitagawa, Susumu.

   Chem. Commun., 2013, 49, 10459-10461. (Inside Back Cover Picture)

 

43) Synthesis, Optical Properties, and Crystal Structures of Dithienostannoles.

   Tanaka, Daiki; Ohshita, Joji; Ooyama, Yousuke; Kobayashi, Norifumi; Higashimura, Hideyuki; Nakanishi, Takayuki; Hasegawa, Yasuchika.

   Organometallics, 2013, 32, 4136-4141.

 

42) Efficient Hydrogen Production and Photocatalytic Reduction of Nitrobenzene over a Visible-Light-Responsive Metal-Organic Framework Photocatalyst.

   Toyao, Takashi; Saito, Masakazu; Horiuchi, Yu; Mochizuki, Katsunori; Iwata, Masatoshi; Higashimura, Hideyuki; Matsuoka, Masaya.

   Catal. Sci. Tech., 2013, 3, 2092-2097.

 

41) Synthesis of Dithienosilole-Based Highly Photoluminescent Donor-Acceptor Type Compounds.

   Ohshita, Joji; Tominaga, Yuta; Tanaka, Daiki; Ooyama, Yousuke; Mizumo, Tomonobu; Kobayashi, Norifumi; Higashimura, Hideyuki.

   Dalton Trans., 2013, 42, 3646-3652.

 

40) Synthesis and Optical Properties of Dithienostiboles.

   Ohshita, Joji; Fujita, Risa; Tanaka, Daiki; Ooyama, Yousuke; Kobayashi, Norifumi; Higashimura, Hideyuki; Yamamoto, Yohsuke.

   Chem. Lett., 2012, 41, 1002-1003.

 

39) Visible-Light-Promoted Photocatalytic Hydrogen Production by Using an Amino-Functionalized Ti(IV) Metal-Organic Framework.

   Horiuchi, Yu; Toyao, Takashi; Saito, Masakazu; Mochizuki, Katsunori; Iwata, Masatoshi; Higashimura, Hideyuki; Anpo, Masakazu; Matsuoka, Masaya.

   J. Phys. Chem. C, 2012, 116, 20848-20853.

 

38) Sol-Gel-Derived Bridged Polysilsesquioxane as a Hydrogen Peroxide Decomposition Catalyst: Immobilization of a Dimanganese Complex and its Improved Thermal Stability.

   Saito, Hitomi; Ishisone, Akira; Horikawa, Yuhei; Ishiyama, Takeshi; Higashimura, Hideyuki; Sugahara, Yoshiyuki.

   Chem. Lett., 2012, 41, 591-592.

 

37) Fused π-Extended Discotic Triangular Porphyrinoids.

   Arnold, Lena; Puniredd, Sreenivasa Reddy; von Malotki, Christian; Pisula, Wojciech; Koshino, Nobuyoshi; Higashimura, Hideyuki; Baumgarten, Martin; Wagner, Manfred; Muellen, Klaus.

   J. Porphyrins Phthalocyanines, 2012, 16, 564-575.

 

36) Synthesis of π-Conjugated Polymers Containing Fluorinated Arylene Units via Direct Arylation: Efficient Synthetic Method of Materials for OLEDs.

   Lu, Wei; Kuwabara, Junpei; Iijima, Takayuki; Higashimura, Hideyuki; Hayashi, Hideki; Kanbara, Takaki.

   Macromolecules, 2012, 45, 4128-4133.

 

35) Synthesis and Optical Properties of a Bis(diphenylphosphino)dithienosilole-Digold(I) Complex.

   Ohshita, Joji; Tominaga, Yuta; Mizumo, Tomonobu; Kuramochi, Yusuke; Higashimura, Hideyuki.

   Heteroatom Chem., 2011, 22, 514-517.

 

34) Triangular Trinuclear Metal-N4 Complexes with High Electrocatalytic Activity for Oxygen Reduction.

   Liu, Ruili; von Malotki, Christian; Arnold, Lena; Koshino, Nobuyoshi; Higashimura, Hideyuki; Baumgarten, Martin; Mullen, Klaus.

   J. Am. Chem. Soc., 2011, 133, 10372-10375.

 

33) Oxidative Coupling Polymerization of p-Alkoxyphenols with Mn(acac)2-Ethylenediamine Catalysts.

   Murakami, Soichiro; Akutsu, Yuuta; Habaue, Shigeki; Haba, Osamu; Higashimura, Hideyuki.

   Natural Science, 2010, 2, 803-808.

 

32) Synthesis of Dithienobismoles as Novel Phosphorescence Materials.

   Ohshita, Joji; Matsui, Shigenori; Yamamoto, Roh; Mizumo, Tomonobu; Ooyama, Yousuke; Harima, Yutaka; Murafuji, Toshihiro; Tao, Keisuke; Kuramochi, Yusuke; Kaikoh, Takashi; Higashimura, Hideyuki.

   Organometallics, 2010, 29, 3239-3241.

 

31) Oxidative Dimerization of Phenol Based on Micromixing in Single- And Two-Phase Systems.

   Okubo, Yoshihito; Higashimura, Hideyuki; Mae, Kazuhiro.

   Ind. Eng. Chem. Res., 2008, 47, 7154-7160.

 

30) Novel Vanadium Catalyst System with Tartaric Acid Salts for Highly Selective Asymmetric Oxidative Coupling Polymerization.

   Murakami, Soichiro; Habaue, Shigeki; Higashimura, Hideyuki.

   Polymer, 2007, 48, 6565-6570.

 

29) Asymmetric Oxidative Coupling Polymerization of Dihydroxynaphthalene Derivatives with Cobalt-Salen Complexes.

   Habaue, Shigeki; Aoyagi, Hideharu; Murakami, Soichiro; Higashimura, Hideyuki.

   Polym. Bull., 2007, 59, 303-310.

 

28) Chain-Growth Polymerization for the Synthesis of Polyfluorene via Suzuki-Miyaura Coupling Reaction from an Externally Added Initiator Unit.

   Yokoyama, Akihiro; Suzuki, Hirofumi; Kubota, Yasuhiro; Ohuchi, Kazuei; Higashimura, Hideyuki; Yokozawa, Tsutomu.

   J. Am. Chem. Soc., 2007, 129, 7236-7237.

 

27) 高選択的不斉酸化カップリング重合によるポリ(ビナフトール)の合成.

   幅上茂樹; 天間知久; 村上総一郎; 東村秀之; 波多野豊平; 平佐哲也.

   高分子論文集, 2006, 63, 297-305.

 

26) フェノール類のラジカル制御酸化重合.

   東村秀之.

   有機合成化学協会誌, 2005, 6, 970-981.

 

25) New Asymmetric Vanadium Catalyst for Highly Selective Oxidative Coupling Polymerization.

   Habaue, Shigeki; Murakami, Soichiro, Higashimura, Hideyuki.

   J. Polym. Sci., Part A: Polym. Chem., 2005, 43, 5872-5878.

 

24) "Radical-Controlled" Oxidative Polymerization of Phenol: Comparison with that of 4-Phenoxyphenol.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Kubota, Masaaki; Kobayashi, Shiro.

   J. Polym. Sci., Part A: Polym. Chem., 2005, 43, 1955-1962.

 

23) Oxidative Coupling Polymerization of 2,3-Dihydroxynaphthalene with Dinuclear-Type Copper(II) Catalyst.

   Habaue, Shigeki; Muraoka, Ryo; Aikawa, Akiko; Murakami, Soichiro; Higashimura, Hideyuki.

   J. Polym. Sci., Part A: Polym. Chem., 2005, 43, 1635-1640.

 

22) Ab Initio Calculation on the Reaction Mechanism of "Radical-Controlled" Oxidative Polymerization of Phenols.

   Kubota, Masaaki; Shiga, Akinobu; Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-oka, Yoshihiko; Uyama, Hiroshi; Kobayashi, Shiro.

   Bull. Chem. Soc. Jap., 2004, 77, 813-818.

 

21) Copper(II) Complexes with a Novel Tris(3,5-diisopropyl-1-pyrazolyl)methane Ligand, [Cu(X2){HC(3,5iPr2pz)3}] (X = Cl and NO3).

   Fujisawa, Kiyoshi; Ono, Tetsuya; Aoki, Hijiri; Ishikawa, Yoko; Miyashita, Yoshitaro; Okamoto, Ken-ichi; Nakazawa, Hiroshi; Higashimura, Hideyuki.

   Inorg. Chem. Commun., 2004, 7, 330-332.

 

20) The Most Hindered Hydrotris(pyrazolyl)borate Ligand, X-ray Structure of Chlorocopper(II) Complex: [Cu(Cl){HB(3-Ad-5-Pripz)3}] as Compared with [Cu(Cl){HB(3-But-5-Pripz)3}].

   Fujisawa, Kiyoshi; Tada, Naoki; Ishikawa, Yoko; Higashimura, Hideyuki; Miyashita, Yoshitaro; Okamoto, Ken-ichi.

   Inorg. Chem. Commun., 2004, 7, 209-212.

 

19) Oxidative Polymerization of Phenols Revisited.

   Kobayashi, Shiro; Higashimura, Hideyuki.

   Prog. Polym. Sci., 2003, 28, 1015-1048.

 

18) チロシナーゼモデル錯体触媒によるフェノール類の高選択的酸化重合.

   東村秀之; 小林四郎.

   高分子論文集, 2002, 59, 319-331.

 

17) Regio- and Chemo-Selective Polymerization of Phenols Catalyzed by Oxidoreductase Enzyme and its Model Complexes.

   Kobayashi, Shiro; Uyama, Hiroshi; Tonami, Hiroyuki; Oguchi, Takahisa; Higashimura, Hideyuki; Ikeda, Ryohei; Kubota, Masaaki.

   Macromol. Symp., 2001, 175, 1-10.

 

16) Coupling Selectivity in the Radical-Controlled Oxidative Polymerization of 4-Phenoxyphenol Catalyzed by (1,4,7-Triisopropyl-1,4,7-triazacyclononane)copper(II) Complex.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Namekawa, Shuhei; Kubota, Masaaki; Shiga, Akinobu; Moro-Oka, Yoshihiko; Uyama, Hiroshi; Kobayashi, Shiro.

   J. Polym. Sci., Part A: Polym. Chem., 2000, 38, 4792-4804.                                              

 

15) New Crystalline Polymers: Poly(2,5-dialkyl-1,4-phenylene oxide)s.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-Oka, Yoshihiko; Namekawa, Shuhei; Kubota, Masaaki; Shiga, Akinobu; Uyama, Hiroshi; Kobayashi, Shiro.

   Macromol. Rapid Commun., 2000, 21, 1121-1124. (Cover Picture

 

14) "Radical-Controlled" Oxidative Polymerization of Phenols: Substituent Effect of Phenol Monomers on the Reaction Rate.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-Oka, Yoshihiko; Namekawa, Shuhei; Kubota, Masaaki; Shiga, Akinobu; Uyama, Hiroshi; Kobayashi, Shiro.

   Polym. Adv. Tech., 2000, 11, 733-738.

 

13) Peroxidase-Catalyzed Oxidative Polymerization of 4,4'-Dihydroxydiphenyl Ether. Formation of α,ω-Hydroxyoligo(1,4-phenylene oxide) through an Unusual Reaction Pathway.

   Fukuoka, Tokuma; Tonami, Hiroyuki; Maruichi, Naoyuki; Uyama, Hiroshi; Kobayashi, Shiro; Higashimura, Hideyuki.

   Macromolecules, 2000, 33, 9152-9155.                                                                    

 

12) "Radical-Controlled" Oxidative Polymerization of 4-Phenoxyphenol Catalyzed by a Dicopper Complex of a Dinucleating Ligand.

   Higashimura, Hideyuki; Kubota, Masaaki; Shiga, Akinobu; Kodera, Masahito; Uyama, Hiroshi.; Kobayashi, Shiro.

   J. Mol. Catal. A: Chem., 2000, 161, 233-237.

 

11) "Radical-Controlled" Oxidative Polymerization of m-Cresol Catalyzed by μ-η2:η2-Peroxo Dicopper(II) Complex.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-oka, Yoshihiko; Kubota, Masaaki; Shiga, Akinobu; Uyama, Hiroshi; Kobayashi, Shiro.

   J. Mol. Catal. A: Chem., 2000, 155, 201-207.

 

10) "Radical-Controlled" Oxidative Polymerization of 4-Phenoxyphenol by a Tyrosinase Model Complex Catalyst to Poly(1,4-phenylene oxide).

   Higashimura, Hideyuki; Kubota, Masaaki; Shiga, Akinobu; Fujisawa, Kiyoshi; Moro-oka, Yoshihiko; Uyama, Hiroshi; Kobayashi, Shiro.

   Macromolecules, 2000, 33, 1986-1995.

 

9) "Radical-Controlled" Oxidative Polymerization of o-Cresol Catalyzed by μ-η2 : η2-Peroxo Dicopper(II) Complex.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-oka, Yoshihiko; Kubota, Masaaki; Shiga, Akinobu; Uyama, Hiroshi; Kobayashi, Shiro.

   Appl. Catal., A: General, 2000, 194-195, 427-433.

 

8) Synthesis, Structure and Reactivity of Phenoxo Copper(II) Complexes, Cu(OAr)(HB(3,5-Pri2pz)3) (Ar = C6H4-4-F, 2,6-Me2C6H3, 2,6-But2C6H3).

   Fujisawa, Kiyoshi; Iwata, Yusaku; Kitajima, Nobumasa; Higashimura, Hideyuki; Kubota, Masaaki; Miyashita, Yoshitaro; Yamada, Yasunori; Okamoto, Ken-Ichi; Moro-Oka, Yoshihiko.

   Chem. Lett., 1999, 8, 739-740.

 

7) Oxidative Polymerization of 2,6-Disubstituted Phenols Catalyzed by Iron-Salen Complex.

   Tonami, Hiroyuki; Uyama, Hiroshi; Kobayashi, Shiro; Higashimura, Hideyuki; Oguchi, Takahisa.

   J. Macromol. Sci., Pure and Appl. Chem., 1999, A36, 719-730.

 

6) Synthesis of a Soluble Polyphenol by Oxidative Polymerization of Bisphenol-A Using Iron-Salen Complex as Catalyst.

   Tonami, Hiroyuki; Uyama, Hiroshi; Oguchi, Takahisa; Higashimura, Hideyuki; Kobayashi, Shiro.

   Polym. Bull., 1999, 42, 125-129.

 

5) Highly Regioselective Oxidative Polymerization of 4-Phenoxyphenol to Poly(1,4-phenylene oxide) Catalyzed by Tyrosinase Model Complexes.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-oka, Yoshihiko; Kubota, Masaaki; Shiga, Akinobu; Terahara, Atsushi; Uyama, Hiroshi;   Kobayashi, Shiro.

   J. Am. Chem. Soc., 1998, 120, 8529-8530.

 

4) Urea as the Most Reactive and Versatile Nitrogen Nucleophile for the Palladium(2+)-Catalyzed Cyclization of Unsaturated Amines.

   Tamaru, Yoshinao; Hojo, Makoto; Higashimura, Hideyuki; Yoshida, Zenichi.

   J. Am. Chem. Soc., 1988, 110, 3994-4002.

 

3) Palladium(II)-Catalyzed Arylchlorination and Oxyarylation of Unsaturated Alcohols.

   Tamaru, Yoshinao; Hojo, Makoto; Higashimura, Hideyuki; Yoshida, Zenichi.

   Angew. Chem. Int. Ed. Engl, 1986, 25, 735-737.

 

2) Palladium(II)-Catalyzed Stereoselective Dilactonization.

   Tamaru, Yoshinao; Higashimura, Hideyuki; Naka, Kensuke; Hojo, Makoto; Yoshida, Zenichi.

   Angew. Chem. Int. Ed. Engl, 1985, 24, 1045-1046.

 

1) A-(Modified B6)-B-[ω-amino(ethylamino)]-β-cyclodextrin as an Artificial B6 Enzyme for Chiral Aminotransfer Reaction.

   Tabushi, Iwao; Kuroda, Yasuhisa; Yamada, Masahiko; Higashimura, Hideyuki; Breslow, Ronald.

   J. Am. Chem. Soc., 1985, 107, 5545-5546.