研究内容

研究コンセプト

 生合成や代謝、光合成や呼吸など、生体は極めて長い時間をかけて精緻に構築された機能を持っています。当研究室では、これら生体の優れた機能をヒントにしながら、世界初の機能性有機材料を創製して、社会を豊かに持続可能にすることを目標にしています。

①人工酵素触媒を用いた高速通信材料の開発

 生体酵素が高選択的に反応制御する機能のみ抽出した人工酵素を用いて、高速通信用の電子部品材料の開発を行っています。大量データを高速に通信できれば、スマホやクラウドの利便性向上だけでなく、車の自動運転や遠隔地の医療など社会をより豊かにすることが期待できます。

②光合成や呼吸酵素を模倣したエネルギー関連材料等の開発

 光合成ではクロロフィルという錯体色素が太陽光を吸収し、呼吸酵素は複核錯体により他電子レドックスを担っています。これらの生体機能を模倣した、グリーン水素の製造や二酸化炭素の利用に関連する材料を研究しています。またEVの航続距離を延ばすよう二次電池の高容量化にも取り組んでいます。

                    

 

       上記に関連する代表論文:

          ①精密重合触媒

            Catal. Sci. Tech. 2023, 13, 4968 (Inside Back Cover)

         Polymer, 2021, 237, 124345

               J. Am. Chem. Soc. 2007, 129, 7236

               J. Am. Chem. Soc. 1998, 120, 8529

 

        ②多核錯体材料

                Chem. Commun. 2014, 50, 677

                Chem. Commun. 2013, 49, 10459

                J. Am. Chem. Soc. 2011, 133, 10372

メンバー

【2023年度】

 PD Md Chanmiya Sheikh

 D2 中野晟志 

 D1 大島貴宏

 M2 武智士門

 M1 内田龍佑

 B4 池田健太朗  髙橋風向  虫明嵩史

 B3 川江友梨奈  木下綾人  塚田雄己  橋本朋佳  山戸緑子

 

【2022年度】

           2022

 PD Md Chanmiya Sheikh

 D1 中野晟志 

 M2 大島貴宏

 M1 武智士門

 B4 青木翼  内田龍佑  杉山靖典  山本脩斗

 B3 池田健太朗  髙橋風向  虫明嵩史

 

【2021年度】

            2020

 PD Md Chanmiya Sheikh

 M2 中野晟志  吉井良太

 M1 大島貴宏

 B4 世良一真  武智士門  田畑宙  西尾隼人  橋口翔  橋本尚吾  福井李菜

 B3 青木翼  内田龍佑  杉山靖典  山本脩斗

 

【2020年度】

            2021

 PD Md Chanmiya Sheikh

 M2 窪田悠斗

 M1 中野晟志  吉井良太

 B4 大島貴宏  沖和子  久高眞帆  谷口奨馬  中岡由実  灰谷凜太郎  藤原輝 

 B3 世良一真  武智士門  田畑宙  西尾隼人  橋口翔  橋本尚吾  福井李菜

 

【2019年度】

IMG_1387    

 M2 馬越薫(硫黄原子を含む新規Ti-MOFの合成)

 M1 窪田悠斗

 B4 中野晟志 七ッ河亮太 藤原裕貴 吉井良太

 B3 大島貴宏  沖和子  久高眞帆  谷口奨馬  中岡由実  灰谷凜太郎  藤原輝 

 

【2018年度】

 M1 馬越薫

 B4 神尾壮樹 窪田悠斗 白水美帆  玉置星都  元平凪人

 B3 中野晟志  七ッ河亮太  藤原裕貴  吉井良太

 

【2017年度】

20180318_083152933_iOS

 B4 田中陸雄 田邉未都輝  則安奏栄

 B3 神尾壮樹  窪田悠斗  白水美帆  玉置星都  元平凪人

原著論文

57) Enzyme model-catalyzed oxidative polymerization of 5-cyano-2-methoxyphenol, a new phenolic monomer with cyano substituent

Shimon Takechi, Takahiro Oshima, Akiyuki Nakano, Hideyuki Higashimura

Chem. Lett. 2024, 53, upae007.

 

56) Enzyme-inspired catalysts with high activity and selectivity for oxidative polymerization of 2-phenylphenol

 Akiyuki Nakano, Vivek S. Raut, Naoki Asao, Akane Ando, Kiyoshi Fujisawa, Hideyuki Higashimura

 Catal. Sci. Technol., 2023, 13, 4968.

 

55) Enzyme Model-catalyzed Oxidative Copolymerization of Phenol while Continuously Adding an Endcap to Multi-branched Poly(phenylene oxide) Showing Low Dielectric Constant

 Akiyuki Nakano, Yuto Kubota, Noboru Osaka, Hideyuki Higashimura

 Chemistry Letters, 2022, 51, 420.

 

54) A new poly(arylene oxide) with an extremely low dielectric constant as a fully aromatic hydrocarbon-type polymer

  Nakano, Akiyuki; Tanabe, Yoichi; Higashimura, Hideyuki

  Polymer, 2021, 237, 124345

 

53) Design and Synthesis of Porous Coordination Polymers with Expanded One-Dimensional Channels and Strongly Lewis-Acidic Sites

   Kajiwara, Takashi; Higashimura, Hideyuki; Higuchi, Masakazu; Kitagawa, Susumu

   ChemNanoMat, 2018, 4, 103-111.

 

52) Construction of Pt complex within Zr-based MOF and its application for hydrogen production under visible-light irradiation.

   Toyao, Takashi; Saito, Masakazu; Dohshi, Satoru; Mochizuki, Katsunori; Iwata, Masatoshi; Higashimura, Hideyuki; Horiuchi, Yu; Matsuoka, Masaya.

   Res. Chem. Intermed., 2016, 42, 7679–7688.

 

51) Synthesis, Properties, and Polymerization of Spiro[(dipyridinogermole) (dithienogermole)].

   Murakami, Kazuya; Ooyama, Yousuke; Higashimura, Hideyuki; Ohshita, Joji.

   Organometallics, 2016, 35, 20−26.

 

50) Cobalt Phenanthroline-Indole Macrocycles as Highly Active Electrocatalysts for Oxygen Reduction.

   Quernheim, Martin; Liang, Haiwei; Su, Qi; Baumgarten, Martin; Koshino, Nobuyoshi; Higashimura, Hideyuki; Müllen, Klaus.

   Chem. Eur. J., 2014, 20, 14178-14183. (Hot Paper)

 

49) A Systematic Study on the Stability of Porous Coordination Polymers against Ammonia.

   Kajiwara, Takashi; Higuchi, Masakazu; Watanabe, Daisuke; Higashimura, Hideyuki; Yamada, Teppei Yamada; Kitagawa, Hiroshi.

   Chem. Eur. J., 2014, 20, 1-8.

 

48) Distibylation of Arylacetylenes for the Formation of Bis(stibyl)ethenes.

   Ohshita, Joji; Tsuchida, Takeshi; Murakami, Kazuya; Ooyama, Yousuke; Nakanishi, Takayuki; Hasegawa, Yasuchika; Kobayashi, Norifumi; Higashimura, Hideyuki.

   Z. Naturforsch., 2014, 69b, 1181-1187

 

47) Development of a Ru Complex-Incorporated MOF Photocatalyst for Hydrogen Production under Visible-Light Irradiation.

   Toyao Takashi; Saito Masakazu; Dohshi Satoru; Mochizuki Katsunori; Iwata Masatoshi; Higashimura, Hideyuki; Horiuchi Yu; Matsuoka Masaya.

   Chem. Commun., 2014, 50, 6779-6781.

 

46) Synthesis and Properties of Nitrogen-Introduced Phenylazomethine Ddendrimer.

   Albrecht, Ken; Higashimura, Hideyuki; Yamamoto, Kimihisa.

   Synth. Commun., 2014, 44, 2239-2247.

 

45) Synthesis of Group 14 Dipyridinometalloles with Enhanced Electron-Deficient Properties and Solid-State Phosphorescence.

   Ohshita, Joji; Murakami, Kazuya; Tanaka, Daiki; Ooyama, Yousuke; Mizumo, Tomonobu; Kobayashi, Norifumi; Higashimura, Hideyuki; Nakanishi, Takayuki; Hasegawa, Yasuchika.

   Organometallics, 2014, 33, 517-521.

 

44) One-Dimensional Alignment of Strong Lewis Acid Sites in a Porous Coordination Polymer.

   Kajiwara, Takashi; Higuchi, Masakazu; Yuasa, Akihiro; Higashimura, Hideyuki; Kitagawa, Susumu.

   Chem. Commun., 2013, 49, 10459-10461. (Inside Back Cover Picture)

 

43) Synthesis, Optical Properties, and Crystal Structures of Dithienostannoles.

   Tanaka, Daiki; Ohshita, Joji; Ooyama, Yousuke; Kobayashi, Norifumi; Higashimura, Hideyuki; Nakanishi, Takayuki; Hasegawa, Yasuchika.

   Organometallics, 2013, 32, 4136-4141.

 

42) Efficient Hydrogen Production and Photocatalytic Reduction of Nitrobenzene over a Visible-Light-Responsive Metal-Organic Framework Photocatalyst.

   Toyao, Takashi; Saito, Masakazu; Horiuchi, Yu; Mochizuki, Katsunori; Iwata, Masatoshi; Higashimura, Hideyuki; Matsuoka, Masaya.

   Catal. Sci. Tech., 2013, 3, 2092-2097.

 

41) Synthesis of Dithienosilole-Based Highly Photoluminescent Donor-Acceptor Type Compounds.

   Ohshita, Joji; Tominaga, Yuta; Tanaka, Daiki; Ooyama, Yousuke; Mizumo, Tomonobu; Kobayashi, Norifumi; Higashimura, Hideyuki.

   Dalton Trans., 2013, 42, 3646-3652.

 

40) Synthesis and Optical Properties of Dithienostiboles.

   Ohshita, Joji; Fujita, Risa; Tanaka, Daiki; Ooyama, Yousuke; Kobayashi, Norifumi; Higashimura, Hideyuki; Yamamoto, Yohsuke.

   Chem. Lett., 2012, 41, 1002-1003.

 

39) Visible-Light-Promoted Photocatalytic Hydrogen Production by Using an Amino-Functionalized Ti(IV) Metal-Organic Framework.

   Horiuchi, Yu; Toyao, Takashi; Saito, Masakazu; Mochizuki, Katsunori; Iwata, Masatoshi; Higashimura, Hideyuki; Anpo, Masakazu; Matsuoka, Masaya.

   J. Phys. Chem. C, 2012, 116, 20848-20853.

 

38) Sol-Gel-Derived Bridged Polysilsesquioxane as a Hydrogen Peroxide Decomposition Catalyst: Immobilization of a Dimanganese Complex and its Improved Thermal Stability.

   Saito, Hitomi; Ishisone, Akira; Horikawa, Yuhei; Ishiyama, Takeshi; Higashimura, Hideyuki; Sugahara, Yoshiyuki.

   Chem. Lett., 2012, 41, 591-592.

 

37) Fused π-Extended Discotic Triangular Porphyrinoids.

   Arnold, Lena; Puniredd, Sreenivasa Reddy; von Malotki, Christian; Pisula, Wojciech; Koshino, Nobuyoshi; Higashimura, Hideyuki; Baumgarten, Martin; Wagner, Manfred; Muellen, Klaus.

   J. Porphyrins Phthalocyanines, 2012, 16, 564-575.

 

36) Synthesis of π-Conjugated Polymers Containing Fluorinated Arylene Units via Direct Arylation: Efficient Synthetic Method of Materials for OLEDs.

   Lu, Wei; Kuwabara, Junpei; Iijima, Takayuki; Higashimura, Hideyuki; Hayashi, Hideki; Kanbara, Takaki.

   Macromolecules, 2012, 45, 4128-4133.

 

35) Synthesis and Optical Properties of a Bis(diphenylphosphino)dithienosilole-Digold(I) Complex.

   Ohshita, Joji; Tominaga, Yuta; Mizumo, Tomonobu; Kuramochi, Yusuke; Higashimura, Hideyuki.

   Heteroatom Chem., 2011, 22, 514-517.

 

34) Triangular Trinuclear Metal-N4 Complexes with High Electrocatalytic Activity for Oxygen Reduction.

   Liu, Ruili; von Malotki, Christian; Arnold, Lena; Koshino, Nobuyoshi; Higashimura, Hideyuki; Baumgarten, Martin; Mullen, Klaus.

   J. Am. Chem. Soc., 2011, 133, 10372-10375.

 

33) Oxidative Coupling Polymerization of p-Alkoxyphenols with Mn(acac)2-Ethylenediamine Catalysts.

   Murakami, Soichiro; Akutsu, Yuuta; Habaue, Shigeki; Haba, Osamu; Higashimura, Hideyuki.

   Natural Science, 2010, 2, 803-808.

 

32) Synthesis of Dithienobismoles as Novel Phosphorescence Materials.

   Ohshita, Joji; Matsui, Shigenori; Yamamoto, Roh; Mizumo, Tomonobu; Ooyama, Yousuke; Harima, Yutaka; Murafuji, Toshihiro; Tao, Keisuke; Kuramochi, Yusuke; Kaikoh, Takashi; Higashimura, Hideyuki.

   Organometallics, 2010, 29, 3239-3241.

 

31) Oxidative Dimerization of Phenol Based on Micromixing in Single- And Two-Phase Systems.

   Okubo, Yoshihito; Higashimura, Hideyuki; Mae, Kazuhiro.

   Ind. Eng. Chem. Res., 2008, 47, 7154-7160.

 

30) Novel Vanadium Catalyst System with Tartaric Acid Salts for Highly Selective Asymmetric Oxidative Coupling Polymerization.

   Murakami, Soichiro; Habaue, Shigeki; Higashimura, Hideyuki.

   Polymer, 2007, 48, 6565-6570.

 

29) Asymmetric Oxidative Coupling Polymerization of Dihydroxynaphthalene Derivatives with Cobalt-Salen Complexes.

   Habaue, Shigeki; Aoyagi, Hideharu; Murakami, Soichiro; Higashimura, Hideyuki.

   Polym. Bull., 2007, 59, 303-310.

 

28) Chain-Growth Polymerization for the Synthesis of Polyfluorene via Suzuki-Miyaura Coupling Reaction from an Externally Added Initiator Unit.

   Yokoyama, Akihiro; Suzuki, Hirofumi; Kubota, Yasuhiro; Ohuchi, Kazuei; Higashimura, Hideyuki; Yokozawa, Tsutomu.

   J. Am. Chem. Soc., 2007, 129, 7236-7237.

 

27) 高選択的不斉酸化カップリング重合によるポリ(ビナフトール)の合成.

   幅上茂樹; 天間知久; 村上総一郎; 東村秀之; 波多野豊平; 平佐哲也.

   高分子論文集, 2006, 63, 297-305.

 

26) フェノール類のラジカル制御酸化重合.

   東村秀之.

   有機合成化学協会誌, 2005, 6, 970-981.

 

25) New Asymmetric Vanadium Catalyst for Highly Selective Oxidative Coupling Polymerization.

   Habaue, Shigeki; Murakami, Soichiro, Higashimura, Hideyuki.

   J. Polym. Sci., Part A: Polym. Chem., 2005, 43, 5872-5878.

 

24) "Radical-Controlled" Oxidative Polymerization of Phenol: Comparison with that of 4-Phenoxyphenol.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Kubota, Masaaki; Kobayashi, Shiro.

   J. Polym. Sci., Part A: Polym. Chem., 2005, 43, 1955-1962.

 

23) Oxidative Coupling Polymerization of 2,3-Dihydroxynaphthalene with Dinuclear-Type Copper(II) Catalyst.

   Habaue, Shigeki; Muraoka, Ryo; Aikawa, Akiko; Murakami, Soichiro; Higashimura, Hideyuki.

   J. Polym. Sci., Part A: Polym. Chem., 2005, 43, 1635-1640.

 

22) Ab Initio Calculation on the Reaction Mechanism of "Radical-Controlled" Oxidative Polymerization of Phenols.

   Kubota, Masaaki; Shiga, Akinobu; Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-oka, Yoshihiko; Uyama, Hiroshi; Kobayashi, Shiro.

   Bull. Chem. Soc. Jap., 2004, 77, 813-818.

 

21) Copper(II) Complexes with a Novel Tris(3,5-diisopropyl-1-pyrazolyl)methane Ligand, [Cu(X2){HC(3,5iPr2pz)3}] (X = Cl and NO3).

   Fujisawa, Kiyoshi; Ono, Tetsuya; Aoki, Hijiri; Ishikawa, Yoko; Miyashita, Yoshitaro; Okamoto, Ken-ichi; Nakazawa, Hiroshi; Higashimura, Hideyuki.

   Inorg. Chem. Commun., 2004, 7, 330-332.

 

20) The Most Hindered Hydrotris(pyrazolyl)borate Ligand, X-ray Structure of Chlorocopper(II) Complex: [Cu(Cl){HB(3-Ad-5-Pripz)3}] as Compared with [Cu(Cl){HB(3-But-5-Pripz)3}].

   Fujisawa, Kiyoshi; Tada, Naoki; Ishikawa, Yoko; Higashimura, Hideyuki; Miyashita, Yoshitaro; Okamoto, Ken-ichi.

   Inorg. Chem. Commun., 2004, 7, 209-212.

 

19) Oxidative Polymerization of Phenols Revisited.

   Kobayashi, Shiro; Higashimura, Hideyuki.

   Prog. Polym. Sci., 2003, 28, 1015-1048.

 

18) チロシナーゼモデル錯体触媒によるフェノール類の高選択的酸化重合.

   東村秀之; 小林四郎.

   高分子論文集, 2002, 59, 319-331.

 

17) Regio- and Chemo-Selective Polymerization of Phenols Catalyzed by Oxidoreductase Enzyme and its Model Complexes.

   Kobayashi, Shiro; Uyama, Hiroshi; Tonami, Hiroyuki; Oguchi, Takahisa; Higashimura, Hideyuki; Ikeda, Ryohei; Kubota, Masaaki.

   Macromol. Symp., 2001, 175, 1-10.

 

16) Coupling Selectivity in the Radical-Controlled Oxidative Polymerization of 4-Phenoxyphenol Catalyzed by (1,4,7-Triisopropyl-1,4,7-triazacyclononane)copper(II) Complex.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Namekawa, Shuhei; Kubota, Masaaki; Shiga, Akinobu; Moro-Oka, Yoshihiko; Uyama, Hiroshi; Kobayashi, Shiro.

   J. Polym. Sci., Part A: Polym. Chem., 2000, 38, 4792-4804.                                              

 

15) New Crystalline Polymers: Poly(2,5-dialkyl-1,4-phenylene oxide)s.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-Oka, Yoshihiko; Namekawa, Shuhei; Kubota, Masaaki; Shiga, Akinobu; Uyama, Hiroshi; Kobayashi, Shiro.

   Macromol. Rapid Commun., 2000, 21, 1121-1124. (Cover Picture

 

14) "Radical-Controlled" Oxidative Polymerization of Phenols: Substituent Effect of Phenol Monomers on the Reaction Rate.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-Oka, Yoshihiko; Namekawa, Shuhei; Kubota, Masaaki; Shiga, Akinobu; Uyama, Hiroshi; Kobayashi, Shiro.

   Polym. Adv. Tech., 2000, 11, 733-738.

 

13) Peroxidase-Catalyzed Oxidative Polymerization of 4,4'-Dihydroxydiphenyl Ether. Formation of α,ω-Hydroxyoligo(1,4-phenylene oxide) through an Unusual Reaction Pathway.

   Fukuoka, Tokuma; Tonami, Hiroyuki; Maruichi, Naoyuki; Uyama, Hiroshi; Kobayashi, Shiro; Higashimura, Hideyuki.

   Macromolecules, 2000, 33, 9152-9155.                                                                    

 

12) "Radical-Controlled" Oxidative Polymerization of 4-Phenoxyphenol Catalyzed by a Dicopper Complex of a Dinucleating Ligand.

   Higashimura, Hideyuki; Kubota, Masaaki; Shiga, Akinobu; Kodera, Masahito; Uyama, Hiroshi.; Kobayashi, Shiro.

   J. Mol. Catal. A: Chem., 2000, 161, 233-237.

 

11) "Radical-Controlled" Oxidative Polymerization of m-Cresol Catalyzed by μ-η2:η2-Peroxo Dicopper(II) Complex.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-oka, Yoshihiko; Kubota, Masaaki; Shiga, Akinobu; Uyama, Hiroshi; Kobayashi, Shiro.

   J. Mol. Catal. A: Chem., 2000, 155, 201-207.

 

10) "Radical-Controlled" Oxidative Polymerization of 4-Phenoxyphenol by a Tyrosinase Model Complex Catalyst to Poly(1,4-phenylene oxide).

   Higashimura, Hideyuki; Kubota, Masaaki; Shiga, Akinobu; Fujisawa, Kiyoshi; Moro-oka, Yoshihiko; Uyama, Hiroshi; Kobayashi, Shiro.

   Macromolecules, 2000, 33, 1986-1995.

 

9) "Radical-Controlled" Oxidative Polymerization of o-Cresol Catalyzed by μ-η2 : η2-Peroxo Dicopper(II) Complex.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-oka, Yoshihiko; Kubota, Masaaki; Shiga, Akinobu; Uyama, Hiroshi; Kobayashi, Shiro.

   Appl. Catal., A: General, 2000, 194-195, 427-433.

 

8) Synthesis, Structure and Reactivity of Phenoxo Copper(II) Complexes, Cu(OAr)(HB(3,5-Pri2pz)3) (Ar = C6H4-4-F, 2,6-Me2C6H3, 2,6-But2C6H3).

   Fujisawa, Kiyoshi; Iwata, Yusaku; Kitajima, Nobumasa; Higashimura, Hideyuki; Kubota, Masaaki; Miyashita, Yoshitaro; Yamada, Yasunori; Okamoto, Ken-Ichi; Moro-Oka, Yoshihiko.

   Chem. Lett., 1999, 8, 739-740.

 

7) Oxidative Polymerization of 2,6-Disubstituted Phenols Catalyzed by Iron-Salen Complex.

   Tonami, Hiroyuki; Uyama, Hiroshi; Kobayashi, Shiro; Higashimura, Hideyuki; Oguchi, Takahisa.

   J. Macromol. Sci., Pure and Appl. Chem., 1999, A36, 719-730.

 

6) Synthesis of a Soluble Polyphenol by Oxidative Polymerization of Bisphenol-A Using Iron-Salen Complex as Catalyst.

   Tonami, Hiroyuki; Uyama, Hiroshi; Oguchi, Takahisa; Higashimura, Hideyuki; Kobayashi, Shiro.

   Polym. Bull., 1999, 42, 125-129.

 

5) Highly Regioselective Oxidative Polymerization of 4-Phenoxyphenol to Poly(1,4-phenylene oxide) Catalyzed by Tyrosinase Model Complexes.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-oka, Yoshihiko; Kubota, Masaaki; Shiga, Akinobu; Terahara, Atsushi; Uyama, Hiroshi;   Kobayashi, Shiro.

   J. Am. Chem. Soc., 1998, 120, 8529-8530.

 

4) Urea as the Most Reactive and Versatile Nitrogen Nucleophile for the Palladium(2+)-Catalyzed Cyclization of Unsaturated Amines.

   Tamaru, Yoshinao; Hojo, Makoto; Higashimura, Hideyuki; Yoshida, Zenichi.

   J. Am. Chem. Soc., 1988, 110, 3994-4002.

 

3) Palladium(II)-Catalyzed Arylchlorination and Oxyarylation of Unsaturated Alcohols.

   Tamaru, Yoshinao; Hojo, Makoto; Higashimura, Hideyuki; Yoshida, Zenichi.

   Angew. Chem. Int. Ed. Engl, 1986, 25, 735-737.

 

2) Palladium(II)-Catalyzed Stereoselective Dilactonization.

   Tamaru, Yoshinao; Higashimura, Hideyuki; Naka, Kensuke; Hojo, Makoto; Yoshida, Zenichi.

   Angew. Chem. Int. Ed. Engl, 1985, 24, 1045-1046.

 

1) A-(Modified B6)-B-[ω-amino(ethylamino)]-β-cyclodextrin as an Artificial B6 Enzyme for Chiral Aminotransfer Reaction.

   Tabushi, Iwao; Kuroda, Yasuhisa; Yamada, Masahiko; Higashimura, Hideyuki; Breslow, Ronald.

   J. Am. Chem. Soc., 1985, 107, 5545-5546.

外部資金

12. 岡山県特別電源所在県科学技術振興事業,代表,超高容量の新規正極材料の開発 ,2023年度

11. 共同研究(化学企業), 代表,2020-2023年度

10. 岡山県特別電源所在県科学技術振興事業,代表,人工酵素触媒を用いた精密重合による高速通信用絶縁材料の開発,2022年度

9. 岡山県特別電源所在県科学技術振興事業,代表,人工酵素触媒を用いた低環境負荷・低コストな精密酸化重合による高性能絶縁材料の開発(2),2021年度

8. 岡山県特別電源所在県科学技術振興事業,代表,人工酵素触媒を用いた低環境負荷・低コストな精密酸化重合による高性能絶縁材料の開発(1),2020年度

7. 科研費基盤C,代表,人工酵素触媒を用いた精密酸化重合による高性能・高機能な芳香族ポリエーテルの合
成,2020-2022年度

6. 岡山県特別電源所在県科学技術振興事業,代表,安価な原料かつ低環境負荷な製法を用いる高性能絶縁材料の開発(2),2019年度

5. 奨学寄付(化学企業), 代表, 2019年度

4. 岡山県特別電源所在県科学技術振興事業,代表,安価な原料かつ低環境負荷な製法を用いる高性能絶縁材料の開発(1),2018年度

3. 科研費基盤C,代表,嵩高い置換基をもつフェノール類のラジカル制御酸化重合,2017-2019年度

2. 革新的触媒による化学品製造プロセス技術開発プロジェクト/二酸化炭素原料化基幹化学品製造プロセス技術開発, グループリーダー. 2013~14年度(経済産業省・NEDOプロジェクト)

1. グリーン・サステイナブルケミカルプロセス基盤技術開発/化学品原料の転換・多様化を可能とする革新グリーン技術の開発/気体原料の高効率利用技術の開発, 業務管理者兼務研究員, 2010~12年度(NEDOプロジェクト)

連絡先

〒700-0005

岡山県岡山市北区理大町1-1

岡山理科大学理学部基礎理学科(B8棟2F)

TEL: 086-256-9476

E-mail: higashimura[@]das.ous.ac.jp([@]を@に)

著書

9) Oxidative Polymerization

  Higashimura, Hideyuki

 Polymers, Polymeric Materials, and Polymer Technology, Routledge, in press.

 

8) Synthesis of Poly(aromatic)s II:​ Enzyme-Model Complexes as Catalyst 

  Higashimura, Hideyuki

  Enzymatic Polymerization towards Green Polymer Chemistry (Green Chemistry and Sustainable Technology), Springer, Chapter 10, P307-341 (2019).

 

7) Oxidative Polymerization.

   Higashimura, Hideyuki; Kobayashi, Shiro.

   Encyclopedia of Polymer Science and Technology, John Wiley & Sons, P1-31 (2016).

 

6) Oxidative Coupling Polymerization.

   Higashimura, Hideyuki.

   Polymer Science A: Comprehensive Reference, Elsevier Science, Vol. 5, P141-173 (2012).

 

5) Platinum-Free Catalysts for Fuel Cell Cathode.

   Koshino, Nobuyoshi; Higashimura, Hideyuki.

   Springer Series in Materials Science, 111(Molecular Catalysts for Energy Conversion), P163-184 (2009).

 

4) フェノール類の酸化重合.

   東村秀之.

   基礎高分子科学, 高分子学会編, 東京科学同人 P294 (2006年).

 

3) ポリフェニレンエーテル.

   東村秀之.

   触媒活用大事典, 触媒活用大事典編集委員会編, 工業調査会 P646-647 (2004).

 

2) Oxidative Polymerization.

   Higashimura, Hideyuki; Kobayashi, Shiro.

   Encyclopedia of Polymer Science and Technology, 3rd Ed., John Wiley & Sons, Vol. 10, P740-764 (2004).

 

1) 酵素に学んだ酸化重合触媒の開発と新規スーパーエンプラ合成への展開

   東村秀之

   ポリマーフロンティア21シリーズ8, 高分子化学と触媒化学のキャッチボール, P101-119 (2001).

総説

11) 遷移金属錯体触媒を用いる芳香族ポリマーの精密合成.

   田中健太, 東村秀之.

   科学と工業, 2009, 83, 18

 

10) 遷移金属錯体触媒で制御された芳香族ポリマーの精密合成.

   東村秀之, 窪田雅明, 大内一栄, 福島大介, 田中健太.

   住友化学, 2008, II, 23.

 

9) 遷移金属錯体触媒を用いる芳香族ポリマーの精密合成.

   東村秀之.

   高分子, 2008, 57, 138.

 

8) Radical-Controlled 酸化重合.

   東村秀之.

   Organometallic News, 2004, 8.

 

7) Reaction Path to Phenol Coupling with Copper Complex.

   Kubota, Masaaki; Higashimura, Hideyuki; Shiga, Akinobu; Fujisawa, Kiyoshi; Uyama, Hiroshi; Kobayashi, Shiro.

   Studies in Surface Science and Catalysis, 2003, 145, 537.

 

6) "Radical-Controlled" Oxidative Polymerization of Phenols.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-oka, Yoshihiko; Kubota, Masaaki; Shiga, Akinobu; Uyama, Hiroshi; Kobayashi, Shiro.

   Studies in Surface Science and Catalysis, 2003, 145, 423.

 

5) Polymer’s Progress.

   Higashimura, Hideyuki; Kobayashi, Shiro.

   Look Japan, 2000, 45, 34.

 

4) スーパーエンプラの環境に優しい・安価な合成法の開発-生体から学んだ高選択性触媒を用いるフェノール類の酸化重合法-.

   東村秀之, 小林四郎.

   化学と工業, 2000, 53, 501.

 

3) スーパーエンジニアリングプラスチックの環境に優しい合成法の開発.

   東村秀之.

   プラスチックスエージ, 2000, 46, 134.

 

2) 低環境負荷・低コストのスーパーエンプラ新規合成法.

   東村秀之, 小林四郎.

   工業材料, 1999, 47, 113.

 

1) Novel Highly-Regioselective Oxidative Polymerization of 4-Phenoxyphenol to Poly(1,4-phenylene oxide) Catalyzed by Tyrosinase Model Complexes.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-oka, Yoshihiko; Kubota, Masaaki; Shiga, Akinobu; Uyama, Hiroshi; Kobayashi, Shiro.

   Studies in Surface Science and Catalysis, 1998, 121, 111.