研究内容

 金属錯体は、金属イオンと有機リガンドの組み合わせにより無限の可能性があり、生体においても呼吸や光合成などの触媒として重要な機能を担っています。当研究室では生体機能に学びながら、芳香族ポリマーを精密合成できる錯体触媒(①)や金属を複数含む錯体材料(②③)により、世界初の有機材料を創製して社会に貢献することを目指します。

     

               参考文献)

               ①精密重合触媒

                    J. Am. Chem. Soc. 1998, 120, 8529-8530

                    J. Am. Chem. Soc. 2007, 129, 7236–7237

              ②③多核錯体材料

                    J. Am. Chem. Soc. 2011, 133, 10372–10375

                    Chem. Commun. 2013, 49, 10459–10461

                    Chem. Commun. 2014, 50, 677–6781

メンバー

【2020年度】

 PD Md Chanmiya Sheikh

 M2 窪田悠斗

 M1 中野晟志  吉井良太

 B4 大島貴宏  沖和子  久高眞帆  谷口奨馬  中岡由実  灰谷凜太郎  藤原輝 

 B3 世良一真  武智士門  田畑宙  西尾隼人  橋口翔  橋本尚吾  福井李菜

 

【2019年度】

IMG_1387    

 M2 馬越薫(硫黄原子を含む新規Ti-MOFの合成)

 M1 窪田悠斗

 B4 中野晟志(人工酵素触媒による2-フェニルフェノールの精密酸化重合における高分子量化)

   七ッ河亮太(酸素酸化重合におけるMOF触媒の作用機構の解明)

   藤原裕貴(金属イオンを担持させたCOFの合成)

   吉井良太(人工光合成を目指した新規Zr-MOF-Sの合成検討)

 B3 大島貴宏  沖和子  久高眞帆  谷口奨馬  中岡由実  灰谷凜太郎  藤原輝 

 

【2018年度】

 M1 馬越薫

 B4 神尾壮樹   (π共役した新規COFの合成検討)

   窪田悠斗  (フェノールの精密酸化重合における高分子量化の検討)

   白水美帆   (酵素モデル触媒の酸化重合におけるフェノールモノマーの置換基効果)

   玉置星都   (フェニルフェノール類の酸化重合への酵素モデル触媒の適用検討)

   元平凪人   (酸素を酸化剤とした酸化重合へのMOF触媒の適用検討)

 B3 中野晟志  七ッ河亮太  藤原裕貴  吉井良太

 

【2017年度】

20180318_083152933_iOS

 B4 田中陸雄       (-フェニルフェノールの酸化重合への酵素モデル触媒の適用検討)

   田邉未都輝   (光触媒機能を有する新規MOFの合成検討)

   則安奏栄       (フェノールの精密酸化重合法の検討)

 B3 神尾壮樹  窪田悠斗  白水美帆  玉置星都  元平凪人

外部資金

9. 特別電源所在県科学技術振興事業,代表,人工酵素触媒を用いた低環境負荷・低コストな精密酸化重合による高性能絶縁材料の開発,2020年度

8. 共同研究(化学企業), 代表, 2020-2021年度

7. 科研費基盤C,代表,人工酵素触媒を用いた精密酸化重合による高性能・高機能な芳香族ポリエーテルの合
成,2020-2022年度

6. 特別電源所在県科学技術振興事業,代表,安価な原料かつ低環境負荷な製法を用いる高性能絶縁材料の開発(2),2019年度

5. 奨学寄付(化学企業), 代表, 2019年度

4. 特別電源所在県科学技術振興事業,代表,安価な原料かつ低環境負荷な製法を用いる高性能絶縁材料の開発(1),2018年度

3. 科研費基盤C,代表,嵩高い置換基をもつフェノール類のラジカル制御酸化重合,2017-2019年度

2. 革新的触媒による化学品製造プロセス技術開発プロジェクト/二酸化炭素原料化基幹化学品製造プロセス技術開発, グループリーダー. 2013~14年度(経済産業省・NEDOプロジェクト)

1. グリーン・サステイナブルケミカルプロセス基盤技術開発/化学品原料の転換・多様化を可能とする革新グリーン技術の開発/気体原料の高効率利用技術の開発, 業務管理者兼務研究員, 2010~12年度(NEDOプロジェクト)

連絡先

〒700-0005

岡山県岡山市北区理大町1-1

岡山理科大学理学部基礎理学科(B8棟2F)

TEL: 086-256-9476

E-mail: higashimura[@]das.ous.ac.jp([@]を@に)

原著論文

53) Design and Synthesis of Porous Coordination Polymers with Expanded One-Dimensional Channels and Strongly Lewis-Acidic Sites

   Kajiwara, Takashi; Higashimura, Hideyuki; Higuchi, Masakazu; Kitagawa, Susumu

   ChemNanoMat, 2018, 4, 103-111.

 

52) Construction of Pt complex within Zr-based MOF and its application for hydrogen production under visible-light irradiation.

   Toyao, Takashi; Saito, Masakazu; Dohshi, Satoru; Mochizuki, Katsunori; Iwata, Masatoshi; Higashimura, Hideyuki; Horiuchi, Yu; Matsuoka, Masaya.

   Res. Chem. Intermed., 2016, 42, 7679–7688.

 

51) Synthesis, Properties, and Polymerization of Spiro[(dipyridinogermole) (dithienogermole)].

   Murakami, Kazuya; Ooyama, Yousuke; Higashimura, Hideyuki; Ohshita, Joji.

   Organometallics, 2016, 35, 20−26.

 

50) Cobalt Phenanthroline-Indole Macrocycles as Highly Active Electrocatalysts for Oxygen Reduction.

   Quernheim, Martin; Liang, Haiwei; Su, Qi; Baumgarten, Martin; Koshino, Nobuyoshi; Higashimura, Hideyuki; Müllen, Klaus.

   Chem. Eur. J., 2014, 20, 14178-14183. (Hot Paper)

 

49) A Systematic Study on the Stability of Porous Coordination Polymers against Ammonia.

   Kajiwara, Takashi; Higuchi, Masakazu; Watanabe, Daisuke; Higashimura, Hideyuki; Yamada, Teppei Yamada; Kitagawa, Hiroshi.

   Chem. Eur. J., 2014, 20, 1-8.

 

48) Distibylation of Arylacetylenes for the Formation of Bis(stibyl)ethenes.

   Ohshita, Joji; Tsuchida, Takeshi; Murakami, Kazuya; Ooyama, Yousuke; Nakanishi, Takayuki; Hasegawa, Yasuchika; Kobayashi, Norifumi; Higashimura, Hideyuki.

   Z. Naturforsch., 2014, 69b, 1181-1187

 

47) Development of a Ru Complex-Incorporated MOF Photocatalyst for Hydrogen Production under Visible-Light Irradiation.

   Toyao Takashi; Saito Masakazu; Dohshi Satoru; Mochizuki Katsunori; Iwata Masatoshi; Higashimura, Hideyuki; Horiuchi Yu; Matsuoka Masaya.

   Chem. Commun., 2014, 50, 6779-6781.

 

46) Synthesis and Properties of Nitrogen-Introduced Phenylazomethine Ddendrimer.

   Albrecht, Ken; Higashimura, Hideyuki; Yamamoto, Kimihisa.

   Synth. Commun., 2014, 44, 2239-2247.

 

45) Synthesis of Group 14 Dipyridinometalloles with Enhanced Electron-Deficient Properties and Solid-State Phosphorescence.

   Ohshita, Joji; Murakami, Kazuya; Tanaka, Daiki; Ooyama, Yousuke; Mizumo, Tomonobu; Kobayashi, Norifumi; Higashimura, Hideyuki; Nakanishi, Takayuki; Hasegawa, Yasuchika.

   Organometallics, 2014, 33, 517-521.

 

44) One-Dimensional Alignment of Strong Lewis Acid Sites in a Porous Coordination Polymer.

   Kajiwara, Takashi; Higuchi, Masakazu; Yuasa, Akihiro; Higashimura, Hideyuki; Kitagawa, Susumu.

   Chem. Commun., 2013, 49, 10459-10461. (Inside Back Cover Picture)

 

43) Synthesis, Optical Properties, and Crystal Structures of Dithienostannoles.

   Tanaka, Daiki; Ohshita, Joji; Ooyama, Yousuke; Kobayashi, Norifumi; Higashimura, Hideyuki; Nakanishi, Takayuki; Hasegawa, Yasuchika.

   Organometallics, 2013, 32, 4136-4141.

 

42) Efficient Hydrogen Production and Photocatalytic Reduction of Nitrobenzene over a Visible-Light-Responsive Metal-Organic Framework Photocatalyst.

   Toyao, Takashi; Saito, Masakazu; Horiuchi, Yu; Mochizuki, Katsunori; Iwata, Masatoshi; Higashimura, Hideyuki; Matsuoka, Masaya.

   Catal. Sci. Tech., 2013, 3, 2092-2097.

 

41) Synthesis of Dithienosilole-Based Highly Photoluminescent Donor-Acceptor Type Compounds.

   Ohshita, Joji; Tominaga, Yuta; Tanaka, Daiki; Ooyama, Yousuke; Mizumo, Tomonobu; Kobayashi, Norifumi; Higashimura, Hideyuki.

   Dalton Trans., 2013, 42, 3646-3652.

 

40) Synthesis and Optical Properties of Dithienostiboles.

   Ohshita, Joji; Fujita, Risa; Tanaka, Daiki; Ooyama, Yousuke; Kobayashi, Norifumi; Higashimura, Hideyuki; Yamamoto, Yohsuke.

   Chem. Lett., 2012, 41, 1002-1003.

 

39) Visible-Light-Promoted Photocatalytic Hydrogen Production by Using an Amino-Functionalized Ti(IV) Metal-Organic Framework.

   Horiuchi, Yu; Toyao, Takashi; Saito, Masakazu; Mochizuki, Katsunori; Iwata, Masatoshi; Higashimura, Hideyuki; Anpo, Masakazu; Matsuoka, Masaya.

   J. Phys. Chem. C, 2012, 116, 20848-20853.

 

38) Sol-Gel-Derived Bridged Polysilsesquioxane as a Hydrogen Peroxide Decomposition Catalyst: Immobilization of a Dimanganese Complex and its Improved Thermal Stability.

   Saito, Hitomi; Ishisone, Akira; Horikawa, Yuhei; Ishiyama, Takeshi; Higashimura, Hideyuki; Sugahara, Yoshiyuki.

   Chem. Lett., 2012, 41, 591-592.

 

37) Fused π-Extended Discotic Triangular Porphyrinoids.

   Arnold, Lena; Puniredd, Sreenivasa Reddy; von Malotki, Christian; Pisula, Wojciech; Koshino, Nobuyoshi; Higashimura, Hideyuki; Baumgarten, Martin; Wagner, Manfred; Muellen, Klaus.

   J. Porphyrins Phthalocyanines, 2012, 16, 564-575.

 

36) Synthesis of π-Conjugated Polymers Containing Fluorinated Arylene Units via Direct Arylation: Efficient Synthetic Method of Materials for OLEDs.

   Lu, Wei; Kuwabara, Junpei; Iijima, Takayuki; Higashimura, Hideyuki; Hayashi, Hideki; Kanbara, Takaki.

   Macromolecules, 2012, 45, 4128-4133.

 

35) Synthesis and Optical Properties of a Bis(diphenylphosphino)dithienosilole-Digold(I) Complex.

   Ohshita, Joji; Tominaga, Yuta; Mizumo, Tomonobu; Kuramochi, Yusuke; Higashimura, Hideyuki.

   Heteroatom Chem., 2011, 22, 514-517.

 

34) Triangular Trinuclear Metal-N4 Complexes with High Electrocatalytic Activity for Oxygen Reduction.

   Liu, Ruili; von Malotki, Christian; Arnold, Lena; Koshino, Nobuyoshi; Higashimura, Hideyuki; Baumgarten, Martin; Mullen, Klaus.

   J. Am. Chem. Soc., 2011, 133, 10372-10375.

 

33) Oxidative Coupling Polymerization of p-Alkoxyphenols with Mn(acac)2-Ethylenediamine Catalysts.

   Murakami, Soichiro; Akutsu, Yuuta; Habaue, Shigeki; Haba, Osamu; Higashimura, Hideyuki.

   Natural Science, 2010, 2, 803-808.

 

32) Synthesis of Dithienobismoles as Novel Phosphorescence Materials.

   Ohshita, Joji; Matsui, Shigenori; Yamamoto, Roh; Mizumo, Tomonobu; Ooyama, Yousuke; Harima, Yutaka; Murafuji, Toshihiro; Tao, Keisuke; Kuramochi, Yusuke; Kaikoh, Takashi; Higashimura, Hideyuki.

   Organometallics, 2010, 29, 3239-3241.

 

31) Oxidative Dimerization of Phenol Based on Micromixing in Single- And Two-Phase Systems.

   Okubo, Yoshihito; Higashimura, Hideyuki; Mae, Kazuhiro.

   Ind. Eng. Chem. Res., 2008, 47, 7154-7160.

 

30) Novel Vanadium Catalyst System with Tartaric Acid Salts for Highly Selective Asymmetric Oxidative Coupling Polymerization.

   Murakami, Soichiro; Habaue, Shigeki; Higashimura, Hideyuki.

   Polymer, 2007, 48, 6565-6570.

 

29) Asymmetric Oxidative Coupling Polymerization of Dihydroxynaphthalene Derivatives with Cobalt-Salen Complexes.

   Habaue, Shigeki; Aoyagi, Hideharu; Murakami, Soichiro; Higashimura, Hideyuki.

   Polym. Bull., 2007, 59, 303-310.

 

28) Chain-Growth Polymerization for the Synthesis of Polyfluorene via Suzuki-Miyaura Coupling Reaction from an Externally Added Initiator Unit.

   Yokoyama, Akihiro; Suzuki, Hirofumi; Kubota, Yasuhiro; Ohuchi, Kazuei; Higashimura, Hideyuki; Yokozawa, Tsutomu.

   J. Am. Chem. Soc., 2007, 129, 7236-7237.

 

27) 高選択的不斉酸化カップリング重合によるポリ(ビナフトール)の合成.

   幅上茂樹; 天間知久; 村上総一郎; 東村秀之; 波多野豊平; 平佐哲也.

   高分子論文集, 2006, 63, 297-305.

 

26) フェノール類のラジカル制御酸化重合.

   東村秀之.

   有機合成化学協会誌, 2005, 6, 970-981.

 

25) New Asymmetric Vanadium Catalyst for Highly Selective Oxidative Coupling Polymerization.

   Habaue, Shigeki; Murakami, Soichiro, Higashimura, Hideyuki.

   J. Polym. Sci., Part A: Polym. Chem., 2005, 43, 5872-5878.

 

24) "Radical-Controlled" Oxidative Polymerization of Phenol: Comparison with that of 4-Phenoxyphenol.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Kubota, Masaaki; Kobayashi, Shiro.

   J. Polym. Sci., Part A: Polym. Chem., 2005, 43, 1955-1962.

 

23) Oxidative Coupling Polymerization of 2,3-Dihydroxynaphthalene with Dinuclear-Type Copper(II) Catalyst.

   Habaue, Shigeki; Muraoka, Ryo; Aikawa, Akiko; Murakami, Soichiro; Higashimura, Hideyuki.

   J. Polym. Sci., Part A: Polym. Chem., 2005, 43, 1635-1640.

 

22) Ab Initio Calculation on the Reaction Mechanism of "Radical-Controlled" Oxidative Polymerization of Phenols.

   Kubota, Masaaki; Shiga, Akinobu; Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-oka, Yoshihiko; Uyama, Hiroshi; Kobayashi, Shiro.

   Bull. Chem. Soc. Jap., 2004, 77, 813-818.

 

21) Copper(II) Complexes with a Novel Tris(3,5-diisopropyl-1-pyrazolyl)methane Ligand, [Cu(X2){HC(3,5iPr2pz)3}] (X = Cl and NO3).

   Fujisawa, Kiyoshi; Ono, Tetsuya; Aoki, Hijiri; Ishikawa, Yoko; Miyashita, Yoshitaro; Okamoto, Ken-ichi; Nakazawa, Hiroshi; Higashimura, Hideyuki.

   Inorg. Chem. Commun., 2004, 7, 330-332.

 

20) The Most Hindered Hydrotris(pyrazolyl)borate Ligand, X-ray Structure of Chlorocopper(II) Complex: [Cu(Cl){HB(3-Ad-5-Pripz)3}] as Compared with [Cu(Cl){HB(3-But-5-Pripz)3}].

   Fujisawa, Kiyoshi; Tada, Naoki; Ishikawa, Yoko; Higashimura, Hideyuki; Miyashita, Yoshitaro; Okamoto, Ken-ichi.

   Inorg. Chem. Commun., 2004, 7, 209-212.

 

19) Oxidative Polymerization of Phenols Revisited.

   Kobayashi, Shiro; Higashimura, Hideyuki.

   Prog. Polym. Sci., 2003, 28, 1015-1048.

 

18) チロシナーゼモデル錯体触媒によるフェノール類の高選択的酸化重合.

   東村秀之; 小林四郎.

   高分子論文集, 2002, 59, 319-331.

 

17) Regio- and Chemo-Selective Polymerization of Phenols Catalyzed by Oxidoreductase Enzyme and its Model Complexes.

   Kobayashi, Shiro; Uyama, Hiroshi; Tonami, Hiroyuki; Oguchi, Takahisa; Higashimura, Hideyuki; Ikeda, Ryohei; Kubota, Masaaki.

   Macromol. Symp., 2001, 175, 1-10.

 

16) Coupling Selectivity in the Radical-Controlled Oxidative Polymerization of 4-Phenoxyphenol Catalyzed by (1,4,7-Triisopropyl-1,4,7-triazacyclononane)copper(II) Complex.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Namekawa, Shuhei; Kubota, Masaaki; Shiga, Akinobu; Moro-Oka, Yoshihiko; Uyama, Hiroshi; Kobayashi, Shiro.

   J. Polym. Sci., Part A: Polym. Chem., 2000, 38, 4792-4804.                                              

 

15) New Crystalline Polymers: Poly(2,5-dialkyl-1,4-phenylene oxide)s.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-Oka, Yoshihiko; Namekawa, Shuhei; Kubota, Masaaki; Shiga, Akinobu; Uyama, Hiroshi; Kobayashi, Shiro.

   Macromol. Rapid Commun., 2000, 21, 1121-1124. (Cover Picture

 

14) "Radical-Controlled" Oxidative Polymerization of Phenols: Substituent Effect of Phenol Monomers on the Reaction Rate.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-Oka, Yoshihiko; Namekawa, Shuhei; Kubota, Masaaki; Shiga, Akinobu; Uyama, Hiroshi; Kobayashi, Shiro.

   Polym. Adv. Tech., 2000, 11, 733-738.

 

13) Peroxidase-Catalyzed Oxidative Polymerization of 4,4'-Dihydroxydiphenyl Ether. Formation of α,ω-Hydroxyoligo(1,4-phenylene oxide) through an Unusual Reaction Pathway.

   Fukuoka, Tokuma; Tonami, Hiroyuki; Maruichi, Naoyuki; Uyama, Hiroshi; Kobayashi, Shiro; Higashimura, Hideyuki.

   Macromolecules, 2000, 33, 9152-9155.                                                                    

 

12) "Radical-Controlled" Oxidative Polymerization of 4-Phenoxyphenol Catalyzed by a Dicopper Complex of a Dinucleating Ligand.

   Higashimura, Hideyuki; Kubota, Masaaki; Shiga, Akinobu; Kodera, Masahito; Uyama, Hiroshi.; Kobayashi, Shiro.

   J. Mol. Catal. A: Chem., 2000, 161, 233-237.

 

11) "Radical-Controlled" Oxidative Polymerization of m-Cresol Catalyzed by μ-η2:η2-Peroxo Dicopper(II) Complex.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-oka, Yoshihiko; Kubota, Masaaki; Shiga, Akinobu; Uyama, Hiroshi; Kobayashi, Shiro.

   J. Mol. Catal. A: Chem., 2000, 155, 201-207.

 

10) "Radical-Controlled" Oxidative Polymerization of 4-Phenoxyphenol by a Tyrosinase Model Complex Catalyst to Poly(1,4-phenylene oxide).

   Higashimura, Hideyuki; Kubota, Masaaki; Shiga, Akinobu; Fujisawa, Kiyoshi; Moro-oka, Yoshihiko; Uyama, Hiroshi; Kobayashi, Shiro.

   Macromolecules, 2000, 33, 1986-1995.

 

9) "Radical-Controlled" Oxidative Polymerization of o-Cresol Catalyzed by μ-η2 : η2-Peroxo Dicopper(II) Complex.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-oka, Yoshihiko; Kubota, Masaaki; Shiga, Akinobu; Uyama, Hiroshi; Kobayashi, Shiro.

   Appl. Catal., A: General, 2000, 194-195, 427-433.

 

8) Synthesis, Structure and Reactivity of Phenoxo Copper(II) Complexes, Cu(OAr)(HB(3,5-Pri2pz)3) (Ar = C6H4-4-F, 2,6-Me2C6H3, 2,6-But2C6H3).

   Fujisawa, Kiyoshi; Iwata, Yusaku; Kitajima, Nobumasa; Higashimura, Hideyuki; Kubota, Masaaki; Miyashita, Yoshitaro; Yamada, Yasunori; Okamoto, Ken-Ichi; Moro-Oka, Yoshihiko.

   Chem. Lett., 1999, 8, 739-740.

 

7) Oxidative Polymerization of 2,6-Disubstituted Phenols Catalyzed by Iron-Salen Complex.

   Tonami, Hiroyuki; Uyama, Hiroshi; Kobayashi, Shiro; Higashimura, Hideyuki; Oguchi, Takahisa.

   J. Macromol. Sci., Pure and Appl. Chem., 1999, A36, 719-730.

 

6) Synthesis of a Soluble Polyphenol by Oxidative Polymerization of Bisphenol-A Using Iron-Salen Complex as Catalyst.

   Tonami, Hiroyuki; Uyama, Hiroshi; Oguchi, Takahisa; Higashimura, Hideyuki; Kobayashi, Shiro.

   Polym. Bull., 1999, 42, 125-129.

 

5) Highly Regioselective Oxidative Polymerization of 4-Phenoxyphenol to Poly(1,4-phenylene oxide) Catalyzed by Tyrosinase Model Complexes.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-oka, Yoshihiko; Kubota, Masaaki; Shiga, Akinobu; Terahara, Atsushi; Uyama, Hiroshi;   Kobayashi, Shiro.

   J. Am. Chem. Soc., 1998, 120, 8529-8530.

 

4) Urea as the Most Reactive and Versatile Nitrogen Nucleophile for the Palladium(2+)-Catalyzed Cyclization of Unsaturated Amines.

   Tamaru, Yoshinao; Hojo, Makoto; Higashimura, Hideyuki; Yoshida, Zenichi.

   J. Am. Chem. Soc., 1988, 110, 3994-4002.

 

3) Palladium(II)-Catalyzed Arylchlorination and Oxyarylation of Unsaturated Alcohols.

   Tamaru, Yoshinao; Hojo, Makoto; Higashimura, Hideyuki; Yoshida, Zenichi.

   Angew. Chem. Int. Ed. Engl, 1986, 25, 735-737.

 

2) Palladium(II)-Catalyzed Stereoselective Dilactonization.

   Tamaru, Yoshinao; Higashimura, Hideyuki; Naka, Kensuke; Hojo, Makoto; Yoshida, Zenichi.

   Angew. Chem. Int. Ed. Engl, 1985, 24, 1045-1046.

 

1) A-(Modified B6)-B-[ω-amino(ethylamino)]-β-cyclodextrin as an Artificial B6 Enzyme for Chiral Aminotransfer Reaction.

   Tabushi, Iwao; Kuroda, Yasuhisa; Yamada, Masahiko; Higashimura, Hideyuki; Breslow, Ronald.

   J. Am. Chem. Soc., 1985, 107, 5545-5546.

著書

8) Synthesis of Poly(aromatic)s II:​ Enzyme-Model Complexes as Catalyst 

  Higashimura, Hideyuki

  Enzymatic Polymerization towards Green Polymer Chemistry (Green Chemistry and Sustainable Technology), Springer, Chapter 10, P307-341 (2019).

 

7) Oxidative Polymerization.

   Higashimura, Hideyuki; Kobayashi, Shiro.

   Encyclopedia of Polymer Science and Technology, John Wiley & Sons, P1-31 (2016).

 

6) Oxidative Coupling Polymerization.

   Higashimura, Hideyuki.

   Polymer Science A: Comprehensive Reference, Elsevier Science, Vol. 5, P141-173 (2012).

 

5) Platinum-Free Catalysts for Fuel Cell Cathode.

   Koshino, Nobuyoshi; Higashimura, Hideyuki.

   Springer Series in Materials Science, 111(Molecular Catalysts for Energy Conversion), P163-184 (2009).

 

4) フェノール類の酸化重合.

   東村秀之.

   基礎高分子科学, 高分子学会編, 東京科学同人 P294 (2006年).

 

3) ポリフェニレンエーテル.

   東村秀之.

   触媒活用大事典, 触媒活用大事典編集委員会編, 工業調査会 P646-647 (2004).

 

2) Oxidative Polymerization.

   Higashimura, Hideyuki; Kobayashi, Shiro.

   Encyclopedia of Polymer Science and Technology, 3rd Ed., John Wiley & Sons, Vol. 10, P740-764 (2004).

 

1) 酵素に学んだ酸化重合触媒の開発と新規スーパーエンプラ合成への展開

   東村秀之

   ポリマーフロンティア21シリーズ8, 高分子化学と触媒化学のキャッチボール, P101-119 (2001).

総説

11) 遷移金属錯体触媒を用いる芳香族ポリマーの精密合成.

   田中健太, 東村秀之.

   科学と工業, 2009, 83, 18

 

10) 遷移金属錯体触媒で制御された芳香族ポリマーの精密合成.

   東村秀之, 窪田雅明, 大内一栄, 福島大介, 田中健太.

   住友化学, 2008, II, 23.

 

9) 遷移金属錯体触媒を用いる芳香族ポリマーの精密合成.

   東村秀之.

   高分子, 2008, 57, 138.

 

8) Radical-Controlled 酸化重合.

   東村秀之.

   Organometallic News, 2004, 8.

 

7) Reaction Path to Phenol Coupling with Copper Complex.

   Kubota, Masaaki; Higashimura, Hideyuki; Shiga, Akinobu; Fujisawa, Kiyoshi; Uyama, Hiroshi; Kobayashi, Shiro.

   Studies in Surface Science and Catalysis, 2003, 145, 537.

 

6) "Radical-Controlled" Oxidative Polymerization of Phenols.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-oka, Yoshihiko; Kubota, Masaaki; Shiga, Akinobu; Uyama, Hiroshi; Kobayashi, Shiro.

   Studies in Surface Science and Catalysis, 2003, 145, 423.

 

5) Polymer’s Progress.

   Higashimura, Hideyuki; Kobayashi, Shiro.

   Look Japan, 2000, 45, 34.

 

4) スーパーエンプラの環境に優しい・安価な合成法の開発-生体から学んだ高選択性触媒を用いるフェノール類の酸化重合法-.

   東村秀之, 小林四郎.

   化学と工業, 2000, 53, 501.

 

3) スーパーエンジニアリングプラスチックの環境に優しい合成法の開発.

   東村秀之.

   プラスチックスエージ, 2000, 46, 134.

 

2) 低環境負荷・低コストのスーパーエンプラ新規合成法.

   東村秀之, 小林四郎.

   工業材料, 1999, 47, 113.

 

1) Novel Highly-Regioselective Oxidative Polymerization of 4-Phenoxyphenol to Poly(1,4-phenylene oxide) Catalyzed by Tyrosinase Model Complexes.

   Higashimura, Hideyuki; Fujisawa, Kiyoshi; Moro-oka, Yoshihiko; Kubota, Masaaki; Shiga, Akinobu; Uyama, Hiroshi; Kobayashi, Shiro.

   Studies in Surface Science and Catalysis, 1998, 121, 111.